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generic cubic, 88 ideal-gas, 66-67 mixing rule for parameters, 378, 521-522, 528-530 PengRobinson, 93-95 RedlicWKwong, 90,206-207 residual properties from, 202-207 Soave/Redlich/Kwong, 93-95 van der Waals, 86, 89 virial, 63-64,66,82-86,97-98,202-204, 377-379 VLE from, 518-534 Equations of balance, 237 Equilibrium, 26,314-315,374,400401, 534-536 criteria for, 355, 370, 374,455456, 536-537 phase (see Phase equilibrium) reaction (see Chemical-reaction equilibrium) Equilibrium constant for chemical reaction, 456468 graph for selected reactions, 460 Eutectic, 561 Exact differential expression, 188 Excess Gibbs energy: and the activity coefficient, 487491, 404-417 empirical expression for: Margules, 408, 415 NRTL, 417418 RedlicWKister, 416 UNIQUAC, 707-708 van Laar, 417 Wilson, 417 Excess property, 386-393 observed behavior, 391-393, 619-622 explanation for, 622-626 partial, 390-39 1,422424 and property change of mixing, 419422 relations among, 390-391 Expansion, in flow process, 249-255 Expansivity, volume, 62, 191-194 Extensive property, 21 First law of thermodynamics: for closed system, 19-23 as applied to ideal gas, 69-82 for flow process, 43-52 Flame temperature, theoretical, 133 Flash calculation, 343-346, 513-516 Flow process, 42-52,235-262 continuity equation for, 43 energy equations for, 43-48, 235-237 entropy balance for, 164-169 mass balance for, 42-43 maximum velocity in, 239-243 momentum principle for, 235 in nozzle, 241-245 in pipe, 239-241 thermodynamic analysis of, 590-599 (See also Compression; Expansion; Throttling process) Fluid mechanics and thermodynamics, 235 Formation reaction, 127 standard Gibbs-energy change of, 462 table of values for, 637-638 standard heat of, 127-129 table of values for, 637438 Freundlich equation, 571 Fuel cell, 495499 calculations for, 498-499 Fugacity, 368-378 calculation of, 369-373 and chemical potential, 374 Fugacity: in chemical-reaction equilibrium, 457, 464-468 equality of, as equilibrium criterion, 374 and Gibbs energy, 368-371 ideal-gas, 369, 375 and phase equilibrium, 370, 375 of species in solution, 375-376 effect of composition on, 400403 and stability, 538-541 Fugacity coefficient, 368-373, 375, 377-384 calculation of, 369-373 from cubic equation of state, 369, 522-526 from generalized correlations, 380-384 in ideal solution, 386 from the virial equation of state, 377-380 and the residual Gibbs energy, 369, 375 Fundamental excess-property relation, 387 Fundamental property relations, 188, 195-197, 375-376 Fundamental residual-property relation, 197, 375 Fusion, latent heat of, 124, 176, 558.

Gas constant, 65 table of values, 630 Gas liquefaction, 304-309 Gas-turbine engine, 285-289 Gases: critical constants for, 632-633 generalized correlations, 95-103, 215-224, 645-661 heat-capacity data for, 635 ideal, 66-82,364-368 P VT relations for, 58-67, 82-103 Generalized correlations: compressibility factor, 95-97, 646449 Generalized correlations: fugacity coefficient, 380-384,658-661 LeeIKesler, 96,216, 380-381,645-661 liquid density, 103-104 residual enthalpy and entropy, 215-224, 650-657 second virial coefficient, 97-98, 382-383 Gibbs adsorption isotherm, 567 GibbsIDuhem equation, 358-359,391, 403404,407,411-414,538-540 for an adsorbate, 567 Gibbs energy, 187 for change of phase, 207-208 differential expression for, 188, 195-196, 353,364,375 and equilibrium, 207-208,455-456, 535-536 and fugacity, 368-371 as generating function, 1955196,388 for ideal gas, 367-368 for ideal solution, 384-385 summary of equations for, 388 (See also Excess Gibbs energy; Residual Gibbs energy) Gibbs's theorem, 362 Heat, 14-15, 18-21,23-24, 148-151 of adsorption, 575-576 of combustion, 129 and entropy, 155-159 of formation, 127-129 table of values for, 637-638 of fusion, 124, 176, 558 latent, 123-125,207-208 of mixing, 421,42&439 of reaction, 126-140 reservoir, 149, 155, 157

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battery, but can run from as low as 5 volts, and as high as 12 volts without a problem Figure 2-3 shows the completed circuit ready to be engaged for hours of great fun at the expense of someone s good night sleep! The circuit is simple enough to hand wire on the underside of the perforated board using some hookup wire and a soldering iron Then, it was tested with a fresh battery and the lights off If you find that the unit will not start when the lights are out, test first to ensure that there is sound output by removing the CDS cell completely, which will cause the unit to start dripping When you reinstall the CDS, the unit will stay quiet until there is absolutely no light at all in the room Even the smallest bit of light will silence the device, so if your target room has any ambient light, you will have to add a resistor in series with the CDS cell in order to make the unit less sensitive to ambient light Try a 50 100K resistor or a variable 100K resistor in series with the CDS cell to help the unit switch on in a dimly lit environment A little experimentation may be necessary, but once working, the dripper will spring into action as soon as the light is off and become silent as soon as someone turns on the light to investigate

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